Before the knife was collected as evidence, it would be photographed where it was found (and possibly fingerprinted). Then it would be placed in a bag, sealed, and the crime scene tech who collected it would sign his name on the seal, It would be recorded as 'Knife, 6-inch, bent blade, bloodstained' on the list of evidence gathered at the scene.
Yes, straightening the blade would be contrary to proper procedure, and when a technician at the crime scene lab went to process it for fingerprints, etc., he would note that the blade had been straightened - which may cause it to be excluded as evidence in the trial.
Straightening it may smear any fingerprints on the knife and could possibly contaminate any DNA - if it was done barehanded.
However, straightening the blade opens all sorts of possibilities. Did a cop or evidence tech do it? Why? Was it accidental or done to contaminate the evidence to hide who committed the crime or to get it thrown out as evidence?
Hope this helps.
Dave